Dioxin, the short name for 2,3,7,8-tetrachlorodibenzo-para-dioxin (2,3,7,8-TCDD), is considered to be one of the most dangerous compounds that pollute our environment. Its chemical structure is made of two aromatic rings joined through a pair of oxygen atoms, as shown in the above drawing. Four chlorine atoms, two on each aromatic ring, are attached at positions 2, 3, 7, and 8. The whole molecule is flat-like and possesses D2h symmetry. If we consider that up to eight chlorine atoms can be attached to the dibenzodioxin (DD) skeleton, then 75 chlorine-substituted DD isomers can be conceived. Dioxin is inextricably linked to environmental pollution from waste incineration and to its incidental formation in chemical plants that are devoted to the production of pesticides [Tuppurainen 2003].
The morning of July 10th (Saturday) 1976 is an ordinary morning just like any other. At 12:37 a cloud blows out from one of the many chimneys of ICMESA, a chemical factory located near the small town of Meda, not far from the city of Seveso. On the next day the mayors of Meda and Seveso are alerted by representatives of ICMESA about the toxic cloud. Soon after, the citizens notice the leaves of trees turning yellow while small animals start to die. Even more frightening are the burns that appear on the faces of children. After more than one week from the incident, people are still wondering what is going on. The presence of dioxin in the environment is being hypothesized and subsequently confirmed on July 20. How was it possible that dioxin escaped from the chemical plant? ICMESA was producing 2,4,5-trichloro-phenol (TCP), a compound that possesses bactericidal properties and finds use as a pesticide. Its synthesis employs 1,2,4,5-tetrachloro-benzene (TCB) as the base compound:
The exothermic reaction increased excessively the pressure of the vessel containing the reactants and, as a result of the malfunctioning of a safety valve, several compounds among which about 30 Kg (!) of TCDD escaped directly into the atmosphere. In the days following the incident the authorities had to estimate the real extent of the disaster so as to quickly undertake the necessary procedures of evacuation, medical assistance, along with securing the contaminated area. Emergency procedures are always based on technical and scientific data, such as the measurement of the amount of TCDD in the blood, fruits, vegetables, and the soil. This, however, was the first large-scale environmental disaster concerned with TCDD contamination and little or no information was available at that time. As Prof. Mocarelli points out, <<Science admits its ignorance within its realm. To admit it publicly is more difficult>>.
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